Opening the scoring came early.. In the 18th minute, Thiago Silva fliked Neymar's corner kick to the back post where David Luiz was position, and he made no mistake finding the back of the net.
However a reply came in the 32nd minute, a defensive error punished emphatically by Alexis Sanchez the Barcelona striker.
The game was tied to a 1-1 draw up till penalty shootouts where the home team won with 3 goals to 2 ending the game to a 4-3 victory for Brazil.
Brazil will now enhance to the quarter-finals.
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